MATERIAL SAFETY DATA SHEET

ISSUED: February 1,  2004 Supersedes Revision, Dated: March 1, 2001

SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT

IDENTIFICATION: X-PANDO PIPE JOINT COMPOUND SPECIAL NO. 2

PRODUCT IDENTIFICATION NE

NUMBER

PRODUCT SEALING JOINTS OF CEMENT LINED PIPES

USE: TO BE WELDED

FDA NA, Not applied for classification.

CLASSIFICATION:

CHEMICAL NAME

AND SYNONYMS: NA

CHEMICAL

FAMILY: NA

Cement Lining Company, Inc.

One Greenway Plaza, Suite 510

Houston, TX 77046

EMERGENCY (609) 394-0150

TELEPHONE NO.

INFORMATION (713) 840-0415

TELEPHONE NO.

SECTION II: COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS INGREDIENTS AND CAS NUMBERS

%

EXPOSURE LIMITS

LD50 (SPECIES & ROUTE)

LC50
Magnesium Oxide fume 1309-48-435-4510 mg/m3 (1); 15 mg/m3 (2) Mouse:  810 mg/kgNE
Magnesium Oxide fume, as respirable dustNE(1); 5 mg/m3 (2)NENE
Graphite (synthetic) 7782-42-58-122 mg/m3 (1,2)NENE
Magnesium Chloride 7786-30-320-25NERat: 2800 mg/kgNE
Silica, crystalline quartz 14808-60-710-150.05 mg/m3 (1); 10 mg/m3 (2)NENE
Strontium Sulfate 14291-01-21-510 mg/m3 (1); 5 mg/m3 (2)NENE
Starch Gum 9004-53-91-5 10 mg/m3 (1); 15 mg/m3 (2)NENE
Magnesium Sulfate 7487-88-91-5NANANA
NOTES: (1) ACGIH TLV (TWA); (2) OSHA PEL (TWA); (3) ACGIH STEL; (4) OSHA STEL; (5) MFR/SUPPLIER TLV; C = Ceiling value.

LD50 Values are via oral Route unless otherwise indicated: (*) SARA (40 CFR 372). Title III, Sec 313 Reportable.

SECTION III: HAZARDS IDENTIFICATION

ROUTES OF ENTRY:

SKIN CONTACT Yes

EYE CONTACT:

Yes

INHALATION:

Yes

INGESTION:

No

POTENTIAL HEALTH EFFECTS:

EYE CONTACT: May cause mechanical irritation if exposed to large amounts of the dust.

SKIN CONTACT: May cause irritation.

INHALATION: May cause irritation to respiratory tract and lung damage if expose is repeated or prolonged.

INGESTION: Taking large amounts may cause nausea.

CARCINOGENICITY: NTP? Yes

IARC? Yes

OSHA? Yes

EFFECTS OF ACUTE EXPOSURE TO PRODUCT: Inhalation of dust may cause irritation. Although unlikely, inhalation of fumes from heated material may cause metal fume fever, a flu-like illness characterized by delayed symptoms of cough, muscle pains chills and nausea. Skin and eye irritation from contact.

EFFECT OF CHRONIC HEALTH HAZARDS: Prolonged or repeated skin contact may cause burns. Prolonged inhalation of dust may lead to lung damage (pneumoconiosis). Symptoms include coughing, difficulty breathing, and the production of black sputum. Symptoms may be delayed until after years of exposure. Dust generated by use of this product contains crystalline silica which is listed by the IARD as a Group 2A carcinogen and by the NTP as a substance which may reasonably be anticipated to be a carcinogen.

MEDICAL CONDITIONS GENERALLY AGRAVATED BY EXPOSURE: Individuals with pulmonary and/or respiratory disease, including, but not limited to, asthma and bronchitis, or subject to eye irritation should be precluded from exposure

 

 

MATERIAL SAFETY DATA SHEET X-PANDO SPECIAL NO. 2 PAGE 2

SECTION IV: FIRST AID MEASURES

EYE CONTACTIrrigate eyes with large amounts of water for at least 15 minutes, while holding the eyelid(s) open. Seek medical attention if irritation persists.
SKIN CONTACTWash the affected area with soap and water. Seek medical attention if irritation persists
INHALATIONMove victim to fresh air and treat symptomatically.
INGESTIONContact local poison control center or physician IMMEDIATELY.

SECTION V: FIRE FIGHTING MEASURES

FLASH POINT ° F NAAUTOIGNITION ° F NALEL % NAUEL % NA
NFPA HAZARD

CLASSIFICATION HEALTH 1

FLAMMABLE 0REACTIVITY 0SPECIFIC HAZARD 0
HMIS HAZARD

CLASSIFICATION HEALTH 1

FLAMMABLE 0REACTIVITY 0SPECIFIC HAZARD 0
WILSON’S RISK SCALE OF

HAZARDS MATERIALS

(R) REACTIVITY 0

(I) INHALATION 1(S) SKIN 0(K) KINDLING, FIRE 0
FLAMMABLE? NOEXPLOSION DATA NA

HAZARDOUS COMBUSTION PRODUCTS: Oxides of magnesium, calcium and carbon.

METHOD OF EXTINCTION: Use medium suitable for surrounding material.
SPECIAL PROCEDURES: Fire-fighters should wear Self-Contained Breathing Apparatus (SCBA).

SECTION VI: ACCIDENTAL RELEASE MEASURES

Wear personal protective equipment (see SECTION VIII). Vacuum or scoop the spilled material into a container for reclamation or proper disposal. Avoid dust generation.

SECTION VII: HANDLING AND STORAGE

Wear personal protective equipment (see SECTION VIII). Store in closed containers in dry areas. Avoid dust generation.

SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION

RESPIRATORY PROTECTION: If TLT or PEL is exceeded or for symptoms of overexposure, wear a NIOSH approved respirator for dust and fumes. Avoid dust generation.

VENTILATION: Local exhaust may be necessary under some handling/use/conditions. Specific needs should be addressed by supervisory or health/safety personnel.

PROTECTIVE EQUIPMENT: If potential for eye contact exists, wear chemical protective glasses. Wear protective gloves and clothing as needed to prevent skin contact. Avoid breathing dust. Use an approved dust respirator if exposure limits are exceeded.

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL

STATE: Solid Powder

APPEARANCE Gray to Black PowderODOR Odorless
SOLUBILITY

IN WATER Appreciable

SPECIFIC GRAVITY

(WATER = 1) 2.56

pH NA

SECTION X: STABILITY AND REACTIVITY

CHEMICAL STABILITY: YESINCOMPATIBILITY WITH OTHER SUBSTANCES: Strong acids, bases
DECOMPOSITION Hydrogen chloride, chlorine, magnesium

PRODUCTS: oxide fume.

HAZARDOUS

POLYMERIZATION: Will not occur.

MATERIAL SAFETY DATA SHEET X-PANDO SPECIAL NO. 2 PAGE 3

SECTION XI: TOXICOLOGICAL INFORMATION

See SECTION II.

SECTION XII: ECOLOGICAL INFORMATION

ECOTOXICITY: NAENVIROMENTAL FATE: NA

SECTION XIII: DISPOSAL CONSIDERATIONS

U.S. EPA WASTE NUMBER Not Regulated

This product, if disposed as received is non-hazardous waste. Disposal must be in accordance with local, state and federal regulations.

SECTION XIV: TRANSPORT INFORMATION

INTERNATIONAL: Not regulatedU.S. EPA Not regulatedU.S. DOT CLASS: Not regulated

SECTION XV: REGULATORY INFORMATION

SARA 311 AND 312 HAZARD CATEGORIES:

IMMEDIATE (ACUTE) HEALTH HAZARD: Not Determined DELAYED (CHRONIC) HEALTH HAZARD: No

FIRE HAZARD: No REACTIVITY HAZARD: No

SUDDEN RELEASE OF PRESSURE: No

SARA SECITON 313 NOTIFICATION: See SECTION XITSCA: All ingredients listed.

OZONE DEPLETING SUBSTANCES (ODS): This product neither contains or is manufactured with OZONE depleting substances subject the labeling requirements of the Clean Air Act Amendments 1990 and CFR Part 82

VOLATILE ORGANIC COMPOUNDS (VOC): Not determined.U.S. STATE REGULATIONS:

VOLATILE ORGANIC COMPOUND (CARB)= ND

EUROPEAN REGULATIONS: EINNECS: Not determined.MITI: Not determined.AICS: Not determined
CANADIAN WHMIS Class D-Poisonous & Infectious Division 2

CLASSIFICATION: Other Effects, Subdivision A-Very Toxic

PRODUCT IDENTIFICATION

NUMBER (PIN): NE

SECTION XVI: OTHER INFORMATION

REVISIONS: Revision Number 6 (1988, 1992, 1995, 1998, 2001,2004)

PREPARATION INFORMATION: Prepared by: Corporate Environmental, Health and Safety Group.

TELEPHONE NUMBER: See SECTION I

The information in the Material Safety Data Sheet should be provided to all who use handle, store, transport, or otherwise be exposed to this product. This information has been prepared for the guidance of plant engineering, operations, and management and for persons working with or handling this product. The information presented in the MSDS is premised upon proper handling and anticipated uses and is for the material without chemical additions/alterations. We believe this information to be reliable and up-to-date as of the date of the last revision, but make no warranty that it is. It is intended for use by persons having technical skill and at their own discretion and risk. Since conditions of use are outside our control, we make no warranties, expressed or implied, and assume no liability in connection with any use of this information. Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents. Any use of this data and information must be determined by the user to be in accordance with federal, state and local laws and regulations. Additionally, if this Material Safety data Sheet is more than three (3) years old, please contact the supplier at the telephone number listed in SECTION I to make certain that this sheet is current. Copyright X-PANDO PRODUCTS COMPANY. License granted to make unlimited copies for internal use only. END OF MSDS

NA = Not Applicable NE = Not Established UN = Unavailable ND = Not Determined